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η 2 -N,O-Chelate complexes LnM[NH 2 CH(CO 2 )CH 2 CH 2 CH 2 CH 2 NH +  3  Cl - ] with L-lysinate in the protected ω-ammonium form (L n M = (allyl) 2 Rh, (2-pyridylphenyl) 2 Ir, (p-cymene)(Cl)Ru, (C 6 Me 6 )(Cl)Ru, (C 5 Me 5 )(Cl)Rh, (C 5 Me 5 )(Cl)Ir) were obtained from chloro bridged complexes. A heterometallic lysinate bridged complex Cp*(Cl)IrNH 2 CH(CO 2 )(CH 2 ) 4 NH 2 Ir(Cl)Cp* is formed with Cp*(Cl)Ir(N,O-lysinate·HCl) and [Cp*RhCl 2 ] 2 .

zeitschrift für naturforschung b

Metallkomplexe mit Biologisch Wichtigen Liganden, CIL [1]. Metallorganische η 2 -N,O-Lysinato-Komplexe / Metal Complexes Of Biologically Important Ligands, Cil [1]. Organometallic η 2 -N,O-Lysinato-Complexes