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Reported here is the isolation and structural elucidation of a new 6,8-cycloeudesmane sesquiterpene, 5-bromo-1-isopropyl-2,5a-dimethyl-decahydro-cyclopropa[a]inden-2-ol (5), alongside the known sesquiterpenes (-)-δ-cadinene (7) and (+)-α-cadinol (8), from the red seaweed Laurencia microcladia Kützing of the Baia di Calenzana, Elba Island. Other than belonging to a rare sesquiterpene class, 5 is the first 6,8-cycloeudesmane sesquiterpene of marine origin.

The First 6,8-Cycloeudesmane Sesquiterpene from a Marine Organism: The Red Seaweed Laurencia microcladia from the Baia di Calenzana, Elba Island