English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Tris(triphenylphosphine)gold(I) chloride was found to form a crystalline phase with two molecules of dichloromethane. In the crystal the chlorine atom is almost fully dissociated from the [(Ph 3 P) 3 Au] +  cation. The gold atom shows only a minor displacement from the plane of the phosphorus atoms (sum of the angles P-Au-P 355.35°; d(Au-Cl) 2.7962(6) Å), very similar to the geometry of the solvent-free crystalline phase. The results are discussed in the context of all known structures for compounds [(Ph 3 P) 3 MCl], M = Cu, Ag, Au. The variations in structure appear to be dominated by electronic (relativistic) rather than steric effects.

Implications of the Results of a Routine Structure Determination: Tris(triphenylphosphine)gold(I) Chloride Bis(dichloromethane)