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Relationships between bond lengths and bond numbers and also between atomic volumes and valencies are derived and parameters for their calculation are given for the s-block, p-block, and d-block metals. From the atomic volumes under pressure, the valencies of three solid lanthanoids have been confirmed or redetermined: La 3; Ce 2. 3. and 4; Yb 2 and 3.

zeitschrift für naturforschung b

Atomvolumen, Atomabstände und chemische Bindung in festen metallischen Elementen/Atomic Volume, Atomic Distances and Chemical Bonding in Solid Metallic Elements