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An isotope effect of about -0.8 Hz at 188 MHz ( - 4 ppb) per two mass units on the  19 F chemical shift in Me 2 GeF 2  due to directly bonded  70 Ge/  72 Ge/ 74 Ge/ 76 Ge has been observed. The analogous isotope effect on the  13 C chemical shift in Me 4 Ge is about -0.045 Hz at 100.6 MHz (-0.45 ppb).

zeitschrift für naturforschung b

Effekt der Germaniumisotope auf die chemische Verschiebung von  19 F in Difluordimethylgerman und von  13 C in Tetramethylgerman / Germanium Isotope Effect on the  19 F Chemical Shift in Difluorodimethylgerm ane and the  13 C Chemical Shift in Tetram ethylgermane