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The N-glycosyl-iminocarboxylate complexes Cp*M(Cl)N(R)=C(R')CO 2  (M = Rh, Ir; R = glycosyl, R ’ = Me, Ph, CH 2 CHMe 2 ) with a chiral metal atom are formed in a template reaction from [Cp*MCl 2 ] 2  (M = Rh, Ir), the 2-keto carboxylic acid and tetra-O-acetyl-β-Dglucosamine, D-glucosamine or D-glucamine as mixtures of two diastereoisomers and were characterized by analytical and spectroscopic methods.

zeitschrift für naturforschung b

Metallkomplexe mit biologisch wichtigen Liganden, CXXXI*. Pentamethylcyclopentadienyl-Halbsandwich-Komplexe von Rhodium und Iridium mit Glycosyl-«-iminocarboxylaten als Chelat-Liganden / M etal C om plexes of Biologically Im portant Ligands, CXXXI*. Pentam ethylcyclopentadienyl Halfsandwich Complexes of Rhodium and Iridium with Glycosyl-a-im inocarboxylates as Chelate Ligands