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The synthesis of the first stable phosphanidovanadium(V) complex  t BuN=V[P(SiMe 3 ) 2 ] 3  is described. The compound has been investigated by  1 H,  13 C , 31 P,  51 V NMR spectroscopy. The results indicate an eighteen-electron complex.

zeitschrift für naturforschung b

t BuN=V[P(SiMe 3 ) 2 ] 3  : Das erste Beispiel eines stabilen Phosphanidovanadium(V)-Komplexes /  t BuN=V[P(SiMe 3 ) 2 ] 3 : The First Example of a Stable Phosphanidovanadium(V) Complex