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Pseudoternary System Bi 2 O 3 /Bi 2 Se 3 /Bi 2 Te 3 , Phase Diagram, Thermodynamic Data The phase diagram of the pseudoternary system Bi 2 O 3 /Bi 2 Se 3 /Bi 2 Te 3  is found to include a quaternary solid solution Bi 2 O 2  (Te x Se 1-x ) and ternary, intermetallic mixed crystals Bi 2 (Te x Se 1-x ) 3 . Using thermodynamic modeling of the solid solutions it is possible to calcu­ late complex heterogeneous equilibria between all phases of this phase diagram. As a result we can thermodynamically describe the observed phase relations:

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Zur Chemie von Mischphasen in komplexen Zustandsdiagrammen Das System Bi 2 O 3 /Bi 2 Se 3 /Bi 2 Te 3 /Chemistry of Mixed Crystals in Complex Phase Diagrams The System Bi 2 O 3 /Bi 2 Se 3 /Bi 2 Te 3