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The synthesis and antimicrobial activity of a series of the title thiones were examined. Reaction of such thiones with hydrazonoyl halides, resulted in ring transformation to give 5-acylhydrazono derivatives of 1,3,4-thiadiazoles. The mechanisms of the studied reactions are discussed.

A Synthesis, Antimicrobial Activity and Heterocyclic Ring Transformation of 5-(Pyrazol-5-yl)-1,3,4-oxadiazole-2(3H)-thiones