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1,3-Dimethyluracil (DMU) forms a complex with copper(I) iodide which shows a green luminescence at λ max  = 505 nm. With PF 6  -  counter ions a photoactive Cu(I)DMU complex is generated which shows a long-wavelength absorption at λ max  = 335 nm. Light absorption by this band leads to a dimerization of DMU to its cyclobutane dimer.

Luminescence Detection and Photodimerization of 1,3-Dimethyluracil Coordinated to Copper(I)