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In (alkyl)di(aryl)(8-dimethylamino-naphth-1-yl)phosphonium salts and in the parent phos­phines, there is no experimental evidence of dative N→P interactions. Conclusions to the contrary are based on the choice of improper standards of comparison

peri-Interactions in Naphthalenes, 3 [1]. On Hypercoordination in 8-Dimethylamino-naphth-1-yl-phosphonium salts and -phosphines