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The thermodynamical data of solid aluminium lanthanum chloride LaAlCl 6  have been obtained by determination of the decomposition equilibria from total pressure measurements. The melting diagram was determined by DTA. The chemical transport of LaCl 3  with AlCl 3  is suggesting the existence of the gaseous complex LaAl 3 Cl 12 . The data are:

zeitschrift für naturforschung b

Thermisches Verhalten von festem LaAlCl 6  und chemischer Transport von LaCl 3  mit AlCl 3 /Thermical Behaviour of Solid LaAlCl 6  and Chemical Transport of LaCl 3  with AlCl 3