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[PhMe 3 N] 4 [Pb 3 Br 10 ] crystallizes with monoclinic symmetry in the space group P 2  1 /c with lattice parameters of a - 1295.5, b - 951.5, c = 2294.7 pm, ß = 110.24° and Z = 2. The unit cell contains eight cations and two [Pb 3 Br 10 ] 4-  anions, each of which shares four vertices with neighbouring anions resulting in a twodimensional anionic partial structure of the Cs 4 Mg 3 F 10  type.

Die Kristallstruktur von [PhMe 3 N] 4 [Pb 3 Br 10 ] / Crystal Structure of [PhMe 3 N] 4 [Pb 3 B r 10 ]