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The reactions of the chloro bridged complexes [(ρ-cymene)RuCl 2 ] 2  and [(C 5 Me 5 )IrCl 2 ] 2  with the anion of 3-(3-pyridyl)-D-alanine (L) afford the N,O-chelate complexes (p-cymene)- Ru(L)(Cl) (1) and (C 5 Me 5 )Ir(L)(Cl) (2). Abstraction of chloride from 1 and 2 using AgSbF 6  gives the dimers [(ρ-cymene)Ru(μ-L) 2 Ru(ρ-cymene)] 2+ (SbF 6 ) 2  (3) and [(C 5 Me 5 )Ir(μ-L) 2 - Ir(C 5 Me 5 )] 2+ (SbF 6 ) 2  (4) with coordination of the pyridine N atom. Complex 4 is formed in high diastereomeric excess. The structure of (C 5 Me 5 )Ir(μ-L) 2 Ir(C 5 Me 5 )]Cl 2  (5) which contains the S Ir R C R C  R Ir  diastereoisomer in the crystal was determined by X-ray diffraction.

Metallkomplexe mit biologisch wichtigen Liganden, CXX [1]. Halbsandwich-Komplexe von Ruthenium(II) und Iridium(III) mit 3-(3-Pyridyl)-D-alaninat