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Ligand exchange reactions of NiCl 2 (PPh 3 ) 2  with O (S )⌒N⌒S ligands were studied. Oxidation products of O⌒N⌒S ligands have been characterized and their structures determined: 3-methyl-4H-benzo[b] [ 1,4]thiazin-2-yl-phenylmethanone / 2-methyl-benzo[d] [ 1,3]thiazole (mixed crystal); [2-iminoisopropyl-thiophenolato(2-)](triphenyl-phosphane)-nickel(II); 1 -phenyl-3-methyl-4-(benzoyl-thiobenzoylhydrazono)-pyrazol-5-thione; [ 1 -phenyl-3-methyl- 4-(benzoyl-thiobenzoylhydrazono)-pyrazol-5-thionato](triphenyl-phosphane)-nickel(II).

Ligandenaustauschreaktionen von NiCl 2 (PPh 3 ) 2 mit O(S)⌒N⌒S-Liganden / Ligand Exchange Reactions of NiCl 2 (PPh 3 ) 2 with O(S )⌒ N ⌒ S Ligands