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Reactions of [Cp 2 WH 2 ] with B(C 6 F 5 ) 3  and Me 2 NB(CF 3 ) 2 , respectively, leads to the formation of the zwitterions [CpWH 3 {η 5 -C 5 H 4 B(C 6 F 5 ) 3 }] (1) and [CpWH 2 {η 5 -C 5 H 4 B(NHMe 2 )(CF 3 ) 2 }] (2). [Cp *  2 WH 2 ] reacts with B(C 6 F 5 ) 3  and tBuBCl 2  to give the saltlike compounds [Cp *  2 WH 3 ][B(C 6 F 5 ) 4 ] (3) and [Cp *  2 WH 3 ][tBuBCl 3 ] (4).

Reaktionen von [(η 5 -C 5 R 5 ) 2 WH 2 ] mit Boranen / Reactions of [(η 5 -C 5 R 5 ) 2 WH 2 ] with Boranes