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α-Amino acid esters can be added to a carbonyl ligand of [CpFe(CO) 3 ] + CF 3 SO 3  -  to give the carbamoyl complexes Cp(OC) 2 Fe-C(O)NHCHRCO 2 R′ (R = H, Me, CHMe 2 , CH 2 Ph; R′ = Et, Me). This type of reaction may be useful for the marking of peptides at the amino end. The crystal structure of Cp(OC) 2 Fe-C(O)NHCH 2 CO 2 Et was determined by X-ray diffraction.

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Metallkomplexe mit biologisch wichtigen Liganden, CXV. Addition von α-Aminosäureestern an [CpFe(CO) 3 ] + : Carbamoylkomplexe Cp(OC) 2 Fe-C(O)NHCHRCO 2 R’ und Kristallstruktur von Cp(OC) 2 Fe-C(O)NHCH 2 CO 2 Et / Metal Complexes of Biologically Important Ligands, CXV. Addition of α-Amino Acid Esters to [CpFe(CO) 3 ] + : Carbamoyl Complexes Cp(OC) 2 Fe-C(O)NHCHRCO 2 R' and Crystal Structure of Cp(OC) 2 Fe-C(O)NHCH 2 CO 2 Et