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The formation of hydrogen bonds to acetonitrile molecules lends stability to the hitherto unknown hydrogenoxonium hexachloroantimonate H 3 O + SbCl 6  -  . The structure of H 3 O + SbCl 6  -  · 2 CH 3 CN was determined on a single crystal. It crystallises in the orthorhombic space group Pmn2( 1) (Nr. 31) with Z = 2, a = 1 12,7( 1 ),b = 988,8( 1) and c = 1036,5( 1) pm.

Kristallstruktur von Hydrogenoxonium-Hexachloroantimonat-Bisacetonitril / Crystal Structure of Hydrogenoxonium Hexachloroantimonate-Bisacetonitrile