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The reaction of CuCl with [CP 2 MoH 2 ] yields the complex [Cu(Cp 2 MoH 2 ) 2 Cl]. An X-ray structure analysis shows that the coordination of the copper(I) ion by two [CP 2 MoH 2 ] ligands and the chloride ion is pseudo-trigonal planar. The hydride ligands were located by using difference Fourier methods. A manifold of reactions took place when an aqueous solution of CUSO 4  was treated with a solution of [Cp 2 MoH 2 ] in dichloromethane in a 1:2 molar ratio. The X-ray structure analysis established a polymeric structure of the complex [Cu(Cp 2 MoH 2 ) 2 Cu(Cp 2 MoH 2 )SO 4 ] n  with two different copper centers.

Copper Complexes with the Ligand [Cp 2 MoH 2 ]