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The phase diagram of the pseudobinary sytem Bi 2 Te 3 /BiCl 3  was investigated by DTA, total pressure measurements, and X-ray phase analysis. Only BiTeCl exists as a ternary phase in this system. The compound melts incongruently at 430 °C. The heat of formation and the standard entropy of BiTeCl were calculated from vapor pressure data:

Untersuchungen zum quasibinären System Bi 2 Te 3 /BiCl 3 /Investigations on the Pseudobinary System Bi 2 Te 3 /BiCl 3