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Single crystals of the hitherto unknown compound SrMnTeO 6  have been prepared from Sr(OH) 2  ·8H 2 O , MnCO 3 (aq) and TeO 2  in air by crystallization below the melt range. X-ray investigations showed hexagonal symmetry, space group D 3  3h  -P6̅2m, lattice constants a = 5.143( 1), c = 5.384(2) A, Z = 1. SrMnTeO 6  is characterized by staggered [(Mn/Te) 6 O 18 ] Kagome layers along [001]. These layers are connected by Sr 2+  ions, resulting in SrO6 prisms isolated from each other. The structure is discussed with respect to the connection of Kagome nets in the quaternary oxides of the Ba 3 Ln 4 O 9  type.

zeitschrift für naturforschung b

Isolierte trigonale SrO 6  – Prismen verknüpfen Kagome-Netze im Strontium-Manganat(IV)-Tellurat(VI): SrMnTeO 6  / Kagomé Layers Connected by Isolated Trigonal SrO 6  Prisms in the Strontium Manganate(IV) Tellurate(VI): SrMnTeO 6  L