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The new compound SrCuTe 2 O 6  has been prepared by quenching single crystals grown from a flux of SrCO 3 , TeO 2  and CuCO 3· Cu(OH) 2 . X-ray investigations show cubic symmetry, space group O 7 -P4 1  32, lattice constant a = 12.473(1), Z = 12. The crystal structure is characterized by square planar CuO 4  polygons and a one-sided open triangular oxygen coordination of Te 4+ , both incorporated in a Sr/O network. The one sided oxygen coordination of tellurium is completed by the lone pair of Te 4+ . Calculations of the Coulomb parts of lattice energy led to the position of the lone pair centre.

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Planare CuO 4 -Polygone und eine einseitig offene Te 4+ O 3 -Koordination in SrCuTe 2 O 6  / Planar CuO 4  Polygons and a One-Sided Open Te 4+ O 3  Coordination in SrCuTe 2 O 6