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The functionalization reactions of 2,2’-bisindolyls with electrophiles and dienophiles gave rise to a group of new protein kinase C inhibitors. Rationalization of structure activity relationships and of some mechanistical aspects concerning the synthesis X ray crystal structures are described for 2,2’-bisindolyl derivatives 1-3 and 6 and for indolo[a]carbazoles 4 and 5.

Synthesis and Crystal Structures of Indole Derivatives and Indolo[2,3-a]carbazoles as Building Blocks to or as Protein Kinase C Inhibitors