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A probable mechanism of the cleavage reaction of thioacetals by copper(II) sulphate adsorbed on silica gel involves: formation of a chelate between sulphur atoms and copper(II), previously coordinated with hydroxyl groups on the silica surface, and the subsequent hydrolysis promoted by hydroxyl groups on the silica gel surface.

On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel