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The reaction of manganese with antimony and sulfur in an aqueous ethylenediamine (en) solution under hydrothermal conditions gives Mn(en) 3 Sb 4 S 7 . The structure of the title compound consists of Mn(en) 3  2+  cations and infinite one-dimensional (Sb 4 S 7  2- )„ anions forming slabs via long secondary interchain Sb···S bonds. A comparison between phases with polymeric (Sb 4 S 7  2-  )„ anions shows in general a trend towards a lower dimensionality of the thioantimonate assembly with increasing cation size. In the title compound the lowest number of interchain Sb···S interactions is observed among other phases with chainlike Sb 4 S 7  2-  anions.

Hydrothermal Synthesis and Crystal Structure of the New Manganese(II) Thioantimonate(III), Mn(en) 3 Sb 4 S 7