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The complex of ReCl(CO) 3 (PhNH-NH 2 ) 2  shows an absorption band at λ max  = 272 nm which is assigned to an IL (intraligand) transition of the coordinated phenylhydrazine. Upon IL excitation the complex undergoes a decomposition with ϕ = 0.03 at λ irr  = 280 nm.

Photoreactivity of Coordinated Phenylhydrazine. Intraligand Excitation of ReCl(CO) 3 (PhNH-NH 2 ) 2