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Bis(η 5  -cyclopentadienyl)tungstendihydride reacts with iPr 2 BCl, BCl 3  or BF 3  to give the saltlike compounds [Cp 2 WH 3 ]iPr 2 BCl 2  (1a), [Cp 2 WH 3 ]BCl 4  (b), and [Cp 2 WH 3 ]BF 4  (c) with a bis(η 5 -cyclopentadienyl)trihydridotungsten cation and a borate anion. Compound 1a crystallizes in the space group P2 1 /n.

zeitschrift für naturforschung b

Zur Umsetzung von Bis(η 5 -cyclopentadienyl)dihydridowolfram mit Halogenboranen / On the Reaction of Bis(η 5 -cyclopentadienyl)tungstendihydride with Boran Halides