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The donor-acceptor complexes [X-I-C 6 H 5 ] −  with X −  = Cl −  and Br −  have been prepared as tetraphenylphosphonium salts from iodobenzene and PPh 4 X in acetonitrile solutions. They form colourless single crystals, which were characterized by crystal structure determinations.

zeitschrift für naturforschung b

Iodbenzol als Lewis-Säure: Synthese und Kristallstrukturen von PPh 4 [Cl-I-C 6 H 5 ] und PPh 4 [Br-I-C 6 H 5 ] / Iodobenzene as Lewis-Acid: Synthesis and Crystal Structures of PPh 4 [Cl-I-C 6 H 5 ] and PPh 4 [Br-I-C 6 H  5 ]