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Monomerie diiodides of 2,4,6-tri(tert-butyl)phenyl = (s-Mes), 2,4,6-triisopropylphenyl = (Trip)-and 2,4-di-tert-butyl-6-methylphenyl = (DBMP)-gallium and -indium were prepared by the reaction of the lithiated aryls with MI 3  (M = Ga, In) in hexane/Et 2 O. s-MesInI 2  (1), s-Mes 2 InI (2), s-MesGaI 2  (3), s-Mes 2 GaI (4), Trip 2 InI (5) and (DBMP) 2 InI (6) were obtained and characterized by their mass and NMR spectra ( 1 H,  13 C), and/or by elemental analyses. An X-ray crystal structure analysis was carried out for 1.

Monomere Iodide von o-substituierten Aryl-Gallium- und Indiumverbindungen / Monomeric Iodides of o-Substituted Aryl Gallium and Indium Compounds