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Treatment of the cymantrene thioether [C 5 (SMe) 5 ]Mn(CO) 3  (IIb) with Na 2 PdCl 4  or K 2 PtCl 4  yields the bimetallic chelate complexes [C 5 (SMe) 5 ]Mn(CO) 3 *MCl 2  (M = Pd (2) or Pt (3)). Similarly, the S,P-chelate complexes [C 5 Cl 2 (SR) 2 (PPh 2 )]Mn(CO) 3 *PdCl 2  (R = Me (4a), Ph (4b)) can be obtained from the corresponding mononuclear cymantrene derivatives and Na 2 PdCl 4  or (PhCN) 2 PdCl 2 . Analysis of the  1 H NMR spectra only allows for the Pt complex the identification of one meso form, which seems to be favoured by 2:1, together with the D,L forms. The crystal structures of [C 5 Cl 2 (SMe) 3 ]Mn(CO) 3 *PdCl 2 (1, C 11 H 9 Cl 4 MnO 3 PdS 3 , triclinic, P1̄, a = 7.617(3) Å , b = 10.528(4) Å ,c = 12.473(5) Å , α = 72.95(3)°, β = 84.94(3)°, γ = 88.75(3)°, V = 952.6(6) Å 3 , Z = 2), 2 (C 13 H 15 Cl 2 MnO 3 PdS 5 , orthorhombic, Pn2 1 /c, a = 12.739(5) Å , b = 9.992(3) Å , c = 16.884(5) Å , V = 2149(1) Å, Z = 4), and 4 (C 23 H 18 Cl 6 MnO 3 PPdS 2 , monoclinic, P2 1 /c, a = 13.199(4) Å , b = 29.198(11) Å , c = 15.921(7) , β - 101.41(3)°, V = 6015(4) Å 3 , Z = 8) are reported and compared with each other and other bimetallic metallocene phosphine and thioether derivatives.

zeitschrift für naturforschung b

Koordinationschemie π-gebundener Cyclopentadienyl-Chalcogeno-Ether, II.  Palladium(II)- und Platin(II)-Komplexe von [C 5 (SMe) 5 ]Mn(CO) 3 , [C 5 Cl 2 (SMe) 3 ]Mn(CO) 3  und [C 5 Cl 2 (SMe) 2 (PPh 2 )]Mn(CO) 3 ./ Coordination Chemistry of π-Bonded Cyclopentadienyl Chalcogeno Ethers, II. Palladium(II) and Platinum(II) Complexes of [C 5 (SMe) 5 ]Mn(CO) 3 , [C 5 Cl 2 (SMe) 3 ]Mn(CO) 3  and [C 5 Cl 2 (SMe) 2 (PPh 2 )]Mn(CO) 3