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Reaction of Ba 3 N 2  with CeN in the stoichiometric ratio 1:3 at 850 °C under an atmosphere of N 2  followed by quenching yields air and moisture sensitive BaCeN 2 . The product crystallizes isotypically to β-RbScO 2  with the anti-TiP type structure in the hexagonal space group P6 3 /mmc with a = 365.06(2), c = 1266.03(3) pm, Z = 2. The structure was determined using X-ray and neutron powder diffraction data. In the structure the Ba 2+  cations occupy trigonal prismatic holes with distances Ba-N = 288(1) pm while the Ce atoms are in octahedral positions with distances C e -N = 242.4(8) pm

BaCeN 2 , ein Bariumnitridocerat(IV) mit einer Struktur vom anti-TiP-Typ / BaCeN 2 , a Bariumnitridocerate(IV ) with a Structure of the anti-TiP Type