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MgNi 2 P was prepared by heating a mixture of the elements and investigated by means of single crystal X-ray methods. The compound crystallizes in an ordered Fe 3 C-type structure (Pnma; a = 6.477(1) Å, b = 6.364(1) Å, c = 5.001(1) Å; Z = 4). Ni and P atoms are linked together to a three-dimensional framework with octogonal tubes running along [010], which are occupied by Mg atoms in the form of stretched zigzag chains.

MgNi 2 P - das erste ternäre Phosphid mit geordneter Fe 3 C-Struktur / MgNi 2 P - The First Ternary Phosphide with an Ordered Fe 3 C Type Structure