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Single crystals of (I): EuBeGd 2 O 5 , (II): Ca 0,4 Sr 0,6 BeSm 2 O 5 , (III): Ba 0,25 Ca 0,75 BeNd 2 O 5  and (IV): Ba 0.36 Sr 0.64 BeNd 2 O 5  were prepared by (I): plasma torch and (II)-(IV ): CO 2 -LASER technique. X-Rayo investigations lead to (I) monoclinic (space group C 5  2h -P2 1 /c, a = 7.126, b = 6.457, c = 9.394 Å , β = 90.40°) and (II)-(IV) orthorhombic symmetry (D 16  2h -Pnma). (II: a = 9.454, b = 7.142, c = 6.490 Å; III: a = 9.508, b = 7.188, c = 6.531 Å; IV: a = 9.642, b = 7.295, c = 6.614 Å). In contrary to the phases M 1-x M′ x BeLn 2 O 5 , EuBeGd 2 O 5  is characterized by an ordered distribution of Eu 2+  and Gd 3+  inside of the Kagomé network.

zeitschrift für naturforschung b

Zur Kenntnis von EuBeGd 2 O 5  mit einem Beitrag über Phasen der Zusammensetzung M 1-x M′ x BeLn 2 O 5 : Ca 0,4 Sr 0,6 BeSm 2 O 5 , Ba 0,25 Ca 0,75 BeNd 2 O 5  und Ba 0,36 Sr 0,64 BeNd 2 O 5  / On EuBeGd 2 O 5  and on Phases of the Composition M 1-x M′ x BeLn 2 O 5 : Ca 0,4 Sr 0,6 BeSm 2 O 5 , Ba 0,25 Ca 0,75 BeNd 2 O 5  and Ba 0,36 Sr 0,64 BeNd 2 O 5