English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The reactions of N-substituted dithiocarbamic acid esters and nickel acetate yield, by partial degradation of the esters, the polynuclear nickel thiolato complexes cyclo-[(μ-SMe) 2 Ni] 6 , 1 and [(μ-SMe) 2 (Ni(MeNHCS 2 )) 2 , 2. Their crystal structures have been determined. The Ni coordination spheres are comprised of four sulfur atoms in a planar arrangement. 1 is a second, highly symmetrical modification of the already known cyclic hexamer Ni 6 (SMe) 12 . In 2 two Ni(PhNHCS 2 ) moieties are bridged to dimers by thiolato groups. Two of these dimers are connected to a tetramer by weak axial Ni-S interactions. Crystal data for 1: monoclinic, space group P2 1 /n, a = 986.1(2), b = 1308.1(3), c = 1228.6(2) pm, β = 96.07(3)°, Z = 2, R = 0.072, R w  = 0.062, 3797 reflections. 2: orthorhombic, space group Pnma, a = 1790.0(4), b = 1806.7(4), c = 934.4(2) pm. Z = 4, R = 0.061, R w  = 0.051, 2079 reflections

zeitschrift für naturforschung b

Strukturen der mehrkernigen nickelthiolato-komplexe [(μ-SMe) 2 (Ni(MeNHCS 2 )) 2 ] und cyclo-[(μ-SMe) 2 Ni] 6  / Structures of Two Polynuclear Nickel-Thiolato-Complexes [(μ-SMe) 2 (Ni(MeNHCS 2 )) 2 ] and cyclo-[(μ-SMe) 2 Ni] 6