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Chiral chelate complexes with dianions of 2-hydroxyiminocarboxylic acids(1) und(2) are obtained by deprotonation of the compoundsandin the presence of a donor ligand (Do=PR 3 , P(OMe) 3 , py). The structure ofhas been determined by X-ray diffraction.

zeitschrift für naturforschung b

Metallkomplexe mit biologisch wichtigen Liganden, LXXII [1]. Halbsandwichkomplexe von Iridium(III) und Ruthenium(II) mit Dianionen von 2-Hydroxyiminocarbonsäuren / Metal Complexes of Biologically Important Ligands, LXXII [1]. Half Sandwich Iridium(III) and Ruthenium(II) Complexes with Dianions of 2-Hydroxyiminocarboxylic Acids