English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Tris(oxamide oxime-N 1 ,N 1′ )cobalt(III) triiodide, [Co(H 2 oxao) 3 ]I 3 , has been synthesized, and its structure determined by single crystal X-ray diffraction at room temperature. The trigonal structure (rhombohedral space group R 3̄ c) was refined by full matrix least-squares to a final R (R w ) of 4.1 (3.5)% for 51 parameters and 911 observed independent reflections. The structure consists exclusively of quasi-octahedral chiral cobaloxime cations, [Co(H 2 oxao) 3 ] 3+ , and iodide anions. This structure is isotypic to that of the homologous Ni-based salt analyzed previously in which, as a matter of specific difference, one H 2 O molecule of crystallization per formula unit is present. Moreover, whereas nickel in the latter salt was identified as Ni II  on the basis of magnetic data, preliminary voltammetric data clearly reveals Co m  in the present salt.

zeitschrift für naturforschung b

Transition Metal Complexes of Oxamide Oxime, 1. Synthesis and X-Ray Crystal Structure of Tris(oxamide oxime-N 1 ,N 1′ )cobalt(III) Triiodide [Co(H 2 oxao) 3 ]I 3