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The isobaric melting and boiling diagrams for the systems: pyridine/methyltrichlorosilane and pyridine/1,1,1-trichloroethane are reproduced. The existence of the congruently melting addition compound CH 3 SiCl 3 · (Pyridin) 2  could be confirmed. Some measurements of the molar volume of mixtures between pyridine and methyltrichlorosilane and pyridine and 1,1,1-trichloroethane, respectively, are reported. For both systems the molar excess volume and for the system pyridine/methyltrichlorosilane the molar excess enthalpie have been calculated as a function of the mole fractions.

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Thermodynamische Untersuchungen der Systeme Pyridin/CH 3 SiCl 3  und Pyridin/Cl 3 CCH 3  / Thermodynamic Examinations of the Systems Pyridine/CH 3 SiCl 3  and Pyridine/Cl 3 CCH 3