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The reactions of Mn(CF 3 COO) 2  (1) with Ν,Ν,N′,N′-tetramethylethylenediamine (tmen), 2,2′-bipyridine (bipy) and triethanolamine (tea) yield three new mononuclear coordination compounds: trans-[Mn(tmen) 2 (CF 3 COO) 2 ] (2), cis-[Mn(bipy) 2 (CF 3 COO) 2 ] (3), and [Mn(tea)2](CF 3 COO) 2  (4). The X-ray structures of the compounds 2, 3, and 4 are described. The seven-coordination of the manganese(II) ion in 4, as well as the inequivalency of the two tea molecules coordinated to Mn(II) make this compound unique.

Syntheses and Structures of Three Mononuclear Coordination Compounds Containing Six- and Seven-Coordinated Manganese(II) Ions