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[{(CO) 4 Co} 2 SnCl 2 ] reacts with silylated chalcogens E(SiMe 3 ) 2  (E = S, Se) to form the compounds [{(CO) 4 Co}4Sn 2 E 2 ] (E = S (1), Se (2)). According to crystal structure determinations 1 and 2 contain planar Sn 2 E 2  rings. The Sn atoms are coordinated nearly tetrahedrally by two bridging chalcogen atoms and two {(CO) 4 Co} groups.

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Neue metallorganisch substituierte Zinn-Chalkogen-Heterocyclen. Synthese und Kristallstrukturen von [ { (CO) 4 Co } 4 Sn 2 E 2 ] (E = S, Se) / New Organometallic Tin Chalcogen Heterocycles. Synthesis and Crystal Structures of [{(CO) 4 Co} 4 Sn 2 E 2 ] (E = S, Se)