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Flavonolatocobalt(III)(salen), a model enzyme-substrate-complex for the quercetinase reaction, was synthesized and its crystal structure determined. C 31 H 23 CoN 2 O 5  · 2 CH 2 Cl 2 , M = 732.35, triclinic, space group P 1̅ , a = 12.463(2), b = 13.270(2), c = 10.041(2) Å, α = 97.89(1)°, β= 108.08(1)°, γ= 83.56(1)°, U = 1559.4 Å 3 , Z = 2.

A Simple Model for the Enzyme-Substrate-Complex of the Quercetinase Reaction. Crystal Structure of Flavonolatocobalt(III)(salen)