English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

A series of 12 bimetallic complexes Cp M(L)[(EC 5 H 4 ) 2 Fe] (M(L) = Rh(PMe 3 ), Ir(PMe 3 ), Ir(PPh 3 ) and Ir(CNtBu); E = S, Se, Te) has been synthesized from the dichlorides Cp M(L)Cl 2 . The new compounds have been characterized by their 1H,  13 C and  31 P NMR spectra in solution. The mass spectra indicate that the two-electron ligand L is preferentially eliminated upon electron-impact. Oxidation by AgBF 4  to give ferrocenium-type cations also occurs readily. An X-ray structure analysis of CpRh(PMe 3 )[(SC 5 H 4 ) 2 Fe] (la) confirms the presence of a 1,1′-ferrocene dithiolate ligand with parallel and ecliptic cyclopentadienyl rings. The long Rh ... Fe (430.4(1) pm) distance rules out any direct interaction between the rhodium center and the iron in the cavity of the ferrocene sandwich.

Pentamethylcyclopentadienyl Halfsandwich Complexes of Rhodium and Iridium Containing 1,1′-Ferrocene Dichalcogenido Ligands