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Benzo-1,3,2-diselenazolylium chloride can be prepared analogously to the corresponding sulfur compound. The cation has been characterized as its perchlorate by X-ray structure analysis. Reduction via the unstable neutral radical state finally affords the nitrogen-free ‘dibenzotetraselenocine’.

Benzo-1,3,2-diselenazol-2-ylium-Salze – Synthese und Reaktivität / Benzo-1,3,2-diselenazolylium Salts – Synthesis and Reactivity