English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The reaction of [(CO) 3 Mn(dppm) 2 Rh(CO)] (1) with H 2 S in dichloromethane yields [(CO) 3 Mn(dppm) 2 (μ-S)Rh(CO)] (2), which is characterized by IR,  31 P{ 1 H},  1 H,  13 C{ 1 H} nmr and mass spectra. The crystal structure of 2 was determined by X-ray diffraction: space group P2 1 /n, Z = 4, a = 1232.6(3), b = 2558.8(4), c = 1640.8(2) pm, β = 97.74(2)°, R/R w  = 0.048/0.057. The dimeric complex shows A-frame structure possessing a bridging sulfur and a semibridging CO group. 2 cannot be oxidized to the corresponding SO 2  bridged complex [(CO) 3 Mn(dppm) 2 (μ-SO 2 )Rh(CO)] (3). The reaction of 2 with SO 2 , however, yields the SO 2  bridged complex [(CO) 2 Mn(dppm) 2 (μ-S)(μ-SO 2 )Rh(CO)] (5); in dichloromethane 2 is readily chlorinated to afford the salt [(CO) 3 Mn(dppm),(μ-S)RhCl]Cl (4).

zeitschrift für naturforschung b

Darstellung, Reaktivität und Kristallstruktur von [(CO) 3 Mn(dppm) 2 (μ-S)Rh(CO)] / Synthesis, Reactivity and Crystal Structure of [(CO) 3 Mn(dppm) 2 (μ-S)Rh(CO)]