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In order to elucidate specific properties of nickel sulfur complexes, redox and addition-elimination reactions of [Ni(′OS 4 ')] 2 , [Ni(′N H S 4 ')] 2 , [Ni(′S 5 ')], [Ni('S 4 —C 5 ')], and [Ni('S 4 —C 3 ')] were investigated ('OS 4′ 2 ' = 2,2'-bis(2-mercaptophenylthio)diethylether(2—), 'N H S 4 ' 2 - = 2,2'-bis(2-mercaptophenylthio)diethylamine(2—), 'S 5 ' 2-  = 2,2'-bis(2-mercaptophenylthio)diethylsulfide(2—), 'S 4 -C 5 ' 2-  = 1,5-bis(2-mercaptophenylthio)pentane(2—), 'S 4 —C 3 ' 2 - = 1,3-bis(2-mercaptophenylthio)propane(2—)).

zeitschrift für naturforschung b

Übergangsmetallkomplexe mit Schwefelliganden, LXXVI Redox- und Additionsreaktionen von Nickelkomplexen mehrzähniger Thioether-Thiolat-Liganden. Röntgenstrukturanalysen von (NMe 4 ) 2 [Ni(′S 2 ′) 2 ] und [Ni(′S 4  – C 3 ′)(PMe 3 )] / Transition Metal Complexes with Sulfur Ligands, LXXVI Redox and Addition Reactions of Nickel Complexes with Multidentate Thioether-Thiolato Ligands. X-Ray Structure Determinations of (NMe 4 ) 2 [Ni(′S 2 ′) 2 ] and [Ni(′S 4 –C 3 ′)(PMe 3 )]