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The title compound 1 has been prepared by the reaction of i-PrInCl 2  with LiCH(SiMe 3 ) 2  in diethylether at -30 °C. The colorless substance 1 was characterized by NMR, IR, and RE spectroscopy, as well as by mass spectrometry. 1 is dimer in solution and the solid state and crystallizes in the space group P2 1 /c with the cell parameters a = 1206.4(3) pm, b = 905.7(2) pm, c = 1591.2(5) pm, and β = 101.18(2)°. The unit cell contains two centrosymmetrical dimeric molecules.

Darstellung und Kristallstruktur von [(Me 3 Si) 2 CH(i-Pr)InCl] 2 / Synthesis and Crystal Structure of [(Me 3 Si) 2 CH(i-Pr)InCl] 2