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The reaction of 1,2,3-diselenaboroles with N–thiosulfinyl-tert-butylamine leads to the 2,1,3-thiaselenaboroles 2 a, b. By insertion of di-iso-propylcarbodiimide the novel six-membered ring 3 is formed. NMR ( 1 H,  11 B,  13 C) and mass spectra are reported and discussed.

zeitschrift für naturforschung b

Notizen: Synthese und Charakterisierung von 3 H-2,1,3-Thiaselenaborolen und eines Carbimino-1,3,2-selenazaborins / Synthesis and Characterization of 3 H-2,1,3-Thiaselenaboroles and a Carbimino-1,3,2-selenazaborine