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The enantioselective hydrosilylation of acetophenone with diphenylsilane in the solvents toluene and CCl 4  was catalysed with a [Rh(COD)Cl] 2 /2-pyridineoxazoline catalyst. The “CCl 4 -effect” (higher enantioselectivity and reactivity) was already confirmed with stoichiometric quantities of CCl 4  with respect to the Rh-catalyst. The influence of other halogenated solvents on the hydrosilylation was investigated.

zeitschrift für naturforschung b

Asymmetrische Katalysen, 71 / Asymmetric Catalyses, 71: Halogenierte Solventien in der Rh-katalysierten Hydrosilylierung mit optisch aktiven 2-Pyridinoxazolinen/ Halogenated Solvents in the Rh-Catalysed Hydrosilylation with Optically Active 2-Pyridineoxazolines