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The syntheses of bis(aluminum)ethane compounds – bis(dichloroaluminum)ethanes to chlorine free bis(diethylaluminum)ethanes 1-10 are described. The connecting ethylene between the two aluminum atoms is identified either as C 2 H 4  (1,2–) or as CH(CH 3 ) (1,1–). The syntheses of Cl 2 AlEt, ethylaluminumsesquichloride and Et 2 AlCl from aluminum, ethylene and AlCl 3  or EtAlCl 2  via bis(aluminum)ethane compounds under various conditions are presented.

zeitschrift für naturforschung b

Bis- und Tris(aluminium)alkan-Verbindungen, II: 1,1- und 1,2-Bis(chloro/ethylaluminium)ethan / Bis- and Tris(aluminum)alkane Compounds, II: 1,1- and 1,2-Bis(chloro/ethylaluminum)ethanes