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Cleavage of β-haloalkyl groups can be performed extremely selectively by cobalt(I)phthalocyanine anion under very mild conditions, qualifying it best in the chemistry of highly sensitive β-lactam antibiotics. This is demonstrated in penicillin and cephalosporin semisyntheses.

zeitschrift für naturforschung b

Äußerst selektive und schonende Abspaltung von β-Halogenalkyl-Gruppen mittels Cobalt(I)phthalocyanin-anion bei Semisynthesen von β Lactam-Antibiotika / Extremely Selective and Mild Cleavage of β-Haloalkyl Groups by Cobalt(I)phthalocyanine Anion in Semisyntheses of β-Lactam Antibiotics