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The three pairs of geminal chloro substituents in hexachloro-cyclotriphosphazene, N 3 P 3 Cl 6 , are stepwise replaced by chelating ferrocene-1,1′-dichalcogenato groups, [Fe(C 5 H 4 E)2.] 2- , to give the spiro-cyclotriphosphazenes N 3 P 3 Cl 6-2n [(EC 5 H 4 ) 2 Fe] n  (n = 1, 2, 3; E = S (a), Se (b)). The molecular structure of P,P′-bis(ferrocene-1,1′-dithiolato)-P″-dichlorocyclotriphosphazene, N 3 P 3 Cl,[(SC 5 H 4 ) 2 Fe] 2 (2a) has been determined.

zeitschrift für naturforschung b

Ferrocen-1,1′-dithiolato- und -diselenato-Derivate des Hexachlor-cyclotriphosphazens / Ferrocene-1,1′-dithiolato and -diselenato Derivatives of Hexachloro-cyclotriphosphazene